6th Singularity Camelot: Land of Emptiness free quest is the best AP & time-saving location to farm Meteor Horseshoe. You'll get about 4~5x Meteor Horseshoe by spending 220AP.
3rd Singularity Okeanos: Caldera Island free quest is the first location you can farm Meteor Horseshoe.
Here is a list of servants that need Meteoric Horseshoe to perform Ascension and Skill Up.
5 Star Servants Tier List: Best Servants [5★]
Best Servants [★4]: 4 Star Tier List
1-3 Star Servants Tier List
Valentine event: Chocolate Lady's Commotion [US 2018]
Nero Claudius (Bride)
FGO Reroll Tier List
Jack the Ripper
Talk on the Heated Sands
Street Choco Maid
Kitchen ☆ Patissiere
Holy Night Supper